Biochemical Symmetrization/ Desymmetrization of Organic Compounds: Dendrimeric Relationship with Molecular Formulas
نویسندگان
چکیده
A criterion for systematization of organic compounds is described. Organic (estimated to 16-20 millions) are three types: (A) symmetric (especially meso and C2 symmetric), (B) possible symmetry generators, i.e. possessing a real or imaginary, but plausible, correspondent: irrechi (from irregular distribution chiral carbons) constitutional), (C) archaic (or primitive) that neither nor generators. Symmetric minority in chemistry. The groups (bio) chemically interchangeable. In preceding papers we have demonstrated almost all natural micromolecular combinations either generators; (primitive) type also represented On the other hand, it should be stressed compounds, both symmetrical (C2 symm.) been found exclusively plants microorganisms, they usually produced from constitutional (constit.) precursors. series symmetrization/desymmetrization reactions presented, proof evidenced can establish new coherent concept biochemistry Symmetrization followed according chemical involved: oxidation, cyclization, esterification, glycosylation, methylation, etc. This approach valid major classes compounds. dendrimeric relationship presented within molecular formulae.
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ژورنال
عنوان ژورنال: Asian journal of chemical sciences
سال: 2023
ISSN: ['2456-7795']
DOI: https://doi.org/10.9734/ajocs/2023/v13i2238